Carboraneradical anions: spectroscopic and electronic properties of a carboraneradical anion with a 2n + 3 skeletal electron count
Literature Information
Mark A. Fox, Carlo Nervi, Antonella Crivello, Paul J. Low
One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable carborane radical anion ([1]−) with a true 2n + 3 cluster electron count; the geometry of ([1]−) features an elongated C⋯C cage distance but no significant π-bonding interactions between the cage and the phenyl substituents.
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