A ‘metallic tape’ stabilized by an unprecedented (μ5-κ2,κ2,κ2,κ1,κ1-) scorpionate binding mode

Literature Information

Publication Date 2007-03-05
DOI 10.1039/B618519C
Impact Factor 6.222
Authors

James R. Gardinier, Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman


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Abstract

The Janus scorpionate ligand, tris(mercaptothiadiazolyl)borate, exhibits extraordinary coordination capacity and versatility, binding from two up to five metal cations as demonstrated by its thallium(I) salt, a compound that serves as a model for metal–surface binding.

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