A ‘metallic tape’ stabilized by an unprecedented (μ5-κ2,κ2,κ2,κ1,κ1-) scorpionate binding mode
Literature Information
James R. Gardinier, Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman
The Janus scorpionate ligand, tris(mercaptothiadiazolyl)borate, exhibits extraordinary coordination capacity and versatility, binding from two up to five metal cations as demonstrated by its thallium(I) salt, a compound that serves as a model for metal–surface binding.
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