New insights into the mechanism of asymmetric hydrogenation catalysed by monophosphonite–rhodium complexes
Literature Information
Ilya D. Gridnev, Cheng Fan, Paul G. Pringle
The solvento complex [Rh(L)2(S)2]+ where L = tBuP(R-binaphthoxo) is shown to be in equilibrium with an η-arene dirhodium complex and only weak, monodentate binding of alkenes is observed; in addition, an intermediate Rh alkyl hydride complex containing two coordinated monophosphonites is unambiguously characterised by NMR.
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Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














