Photodimerization of acenaphthylene within a nanocapsule: excited state lifetime dependent dimer selectivity

Literature Information

Publication Date 2006-12-14
DOI 10.1039/B615937K
Impact Factor 6.222
Authors

Lakshmi S. Kaanumalle, V. Ramamurthy


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Abstract

Direct excitation of acenaphthylene molecules included in a syn fashion within the octa acid nanocapsule dimerizes quantitatively to a syn dimer, and upon triplet sensitization, yields both syn and anti dimers probably by reacting within and outside the capsule.

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