Asymmetric total synthesis of martinelline and martinellic acid
Literature Information
Shuhei Ikeda, Masatoshi Shibuya, Yoshiharu Iwabuchi
Herein, we describe the first asymmetric total synthesis of (–)-martinelline ((–)-2) and the second total synthesis of (–)-martinellic acid ((–)-1) by employing a tandem Mukaiyama–Mannich reaction/aminal cyclization as the key step.
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