Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph˙ radical

Literature Information

Publication Date 2006-06-27
DOI 10.1039/B606322E
Impact Factor 6.222
Authors

Mario C. Foti, Carmelo Daquino


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Abstract

The kinetics and energetics of the reversible reaction of phenols with the dpph˙ radical have been studied; steric shielding of the divalent N by the o-NO2 in dpph˙ seems to be the main cause of the entropic barriers of this reaction.

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