Ruthenium hydroxide on magnetite as a magnetically separable heterogeneous catalyst for liquid-phase oxidation and reduction

Literature Information

Publication Date 2006-07-05
DOI 10.1039/B603204D
Impact Factor 10.182
Authors

Miyuki Kotani, Takeshi Koike


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Abstract

Three kinds of reactions, (i) aerobic oxidation of alcohols, (ii) aerobic oxidation of amines, and (iii) reduction of carbonyl compounds to alcohols using 2-propanol as a hydrogen donor, could efficiently be promoted by an easily prepared ruthenium hydroxide catalyst on magnetite (Ru(OH)x/Fe3O4). A wide variety of substrates including aromatic, aliphatic, and heterocyclic ones could be converted to the desired products in high to excellent yields without any additives such as bases and electron transfer mediators. After the reaction, the catalyst/product(s) separation could be easily achieved with a permanent magnet and more than 99% of Ru(OH)x/Fe3O4 catalyst could usually be recovered for each reaction. The catalysis for these reactions was intrinsically heterogeneous, and Ru(OH)x/Fe3O4 recovered after these reactions could be reused without appreciable loss of the catalytic performance.

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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

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