Unusual carbon–sulfur bond cleavage in the reaction of a new type of bulky hexathioether with a zerovalent palladium complex
Literature Information
Daisuke Shimizu, Nobuhiro Takeda, Norihiro Tokitoh
The reaction of a bulky hexathioether, TbtS(o-Phen)S(o-Phen)SS(o-Phen)S(o-Phen)STbt (o-Phen = o-phenylene, Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl) (1), with 3 molar amounts of Pd(PPh3)4 afforded trinuclear palladium complex 4 bridged by two benzenedithiolato ligands via a three-step palladium insertion reaction into one sulfur–sulfur and two carbon–sulfur bonds of 1.
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