Isolation and structure of a silicocationic species with 1,3-aryl bridging between silicon atoms: a bis-silylated benzenium ion or a bridging Ph group?

Literature Information

Publication Date 2005-11-04
DOI 10.1039/B513203G
Impact Factor 6.222
Authors

Nicholas Choi, Paul D. Lickiss, Mary McPartlin, Phindile C. Masangane, Guilaine L. Veneziani


View Original

Abstract

Hydride abstraction from (Me3Si)3CSiMePhH by Ph3C+ affords the cation [(Me3Si)2CSiMe2–Ph–SiMe2]+, which is shown by X-ray crystallography to contain the first structurally characterised example of a Ph group bridging between two silicon atoms.

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