Ruthenium trihydrides with N-heterocyclic carbeneligands: effects on quantum mechanical exchange coupling

Literature Information

Publication Date 2005-11-04
DOI 10.1039/B512760B
Impact Factor 6.222
Authors

Aled L. Jones, G. Sean McGrady, Peter Sirsch, Jonathan W. Steed


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Abstract

Ruthenium trihydrides containing N-heterocyclic carbene ligands display large quantum mechanical exchange couplings in their 1H NMR spectra: DFT calculations are used to explore this phenomenon and to compare them to their phosphine congeners.

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