Stabilisation of a paramagnetic BH4−-bridged dinickel(ii) complex by a macrodinucleating hexaaza-dithiophenolate ligand

Literature Information

Publication Date 2005-11-23
DOI 10.1039/B512744K
Impact Factor 6.222
Authors

Yves Journaux, Vasile Lozan, Julia Klingele, Berthold Kersting


View Original

Abstract

The first paramagnetic borohydrido-bridged dinuclear nickel(II) complex, [(L)NiII2(μ1,3-BH4)]+, stabilised by a sterically demanding hexaaza-dithiophenolate macrocycle, has been obtained by the reaction of [(L)NiII2(μ-ClO4)]+ with NnBu4BH4.

Related Literature

Spectrofluorimetric study of estrogen–cyclodextrin inclusion complexes in aqueous systems

Rocío L. Pérez, Graciela M. Escandar

2012-12-17 Paper

DOI: 10.1039/C2AN36395J

Front cover

Cover

DOI: 10.1039/C3AN90058D

Selective sensing of vapors of similar dielectric constants using peptide-capped gold nanoparticles on individual multivariable transducers

Nandini Nagraj, Joseph M. Slocik, David M. Phillips, Nancy Kelley-Loughnane, Rajesh R. Naik, Radislav A. Potyrailo

2013-04-17 Paper

DOI: 10.1039/C3AN00088E

Front cover

Cover

DOI: 10.1039/C2AN90118H

Rapid photochemical surface patterning of proteins in thiol–ene based microfluidic devices

Josiane P. Lafleur, Radoslaw Kwapiszewski, Thomas G. Jensen, Jörg P. Kutter

2012-11-20 Paper

DOI: 10.1039/C2AN36424G

Editorial Board profiles

2012-11-21 Editorial

DOI: 10.1039/C2AN90110B

A novel colorimetric biosensor for monitoring and detecting acute toxicity in water

Junfeng Zhai, Daming Yong, Jing Li, Shaojun Dong

2012-11-01 Paper

DOI: 10.1039/C2AN36160D

A graphene-based label-free voltammetric immunosensor for sensitive detection of the egg allergen ovalbumin

Shimaa Eissa, Lamia L'Hocine, Mohamed Siaj, Mohammed Zourob

2013-04-23 Paper

DOI: 10.1039/C3AN36883A

Analysis of single particle photodegradation using photothermal infrared microspectroscopy

Jonathan G. Moffat, Mark D. Eddleston, Peter S. Belton, William Jones, Duncan Q. M. Craig

2013-02-18 Paper

DOI: 10.1039/C3AN36686C

Subcellular spectroscopic markers, topography and nanomechanics of human lung cancer and breast cancer cells examined by combined confocal Raman microspectroscopy and atomic force microscopy

Gerald D. McEwen, Yangzhe Wu, Mingjie Tang, Xiaojun Qi, Zhongmiao Xiao, Sherry M. Baker, Tian Yu, Timothy A. Gilbertson, Daryll B. DeWald, Anhong Zhou

2012-11-05 Paper

DOI: 10.1039/C2AN36359C

You might also like

Compound Q&A

What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?

When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...

16712-20-2Lithium chloride hyd...
Compound Q&A

Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?

4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...

690261-92-84-(4H-1,2,4-Triazol-...
Compound Q&A

How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?

Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...

16733-85-01,3-Thiazole-2-carbo...
Compound Q&A

What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?

5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...

934175-58-35-(Difluoromethyl)-2...
Compound Q&A

How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?

Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...

22288-79-5Methyl 3-acetamido-2...
Compound Q&A

What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?

4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...

34846-65-64-Isoquinolinecarbon...
Compound Q&A

How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?

Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...

877309-59-6Methyl 1H-1,2,3-tria...
Compound Q&A

What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?

6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...

1160791-13-86-Bromo[1,3]thiazolo...
Compound Q&A

Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?

(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...

23651-95-8(2S,3S)-2-Ammonio-3-...
Compound Q&A

What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?

7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....

1293987-84-47-bromo-3-methyl-3,4...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.