Selective oxidative para C–C dimerization of 2,6-dimethylphenol
Literature Information
Christophe Boldron, Guillem Aromí, Ger Challa, Patrick Gamez, Jan Reedijk
Mechanistic investigations on the oxidative coupling of 2,6-dimethylphenol have led to the development of a selective and efficient procedure to prepare 3,5,3′,5′-tetramethyl-biphenyl-4,4′-diol, via a C–C coupling, mediated by a hypervalent form of iodine, i.e. (diacetoxyiodo)benzene and for which a mechanism is proposed.
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