Surprising reactions of a 2H-azaphosphirene complex with a silylene

Literature Information

Publication Date 2005-09-05
DOI 10.1039/B509567K
Impact Factor 6.222
Authors

Emanuel Ionescu, Barbara Gehrhus, Peter B. Hitchcock, Martin Nieger, Rainer Streubel


View Original

Abstract

Reaction of the 2H-azaphosphirene complex 1 with the silylene 5 yielded the bicyclic carbene complex 9 as sole product at ambient temperature; the reaction was less selective at elevated temperatures; additionally, the synthesis and structure of the first 1,2,4,3-azadiphosphasilol-5-ene complex 11 is presented.

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