Metal-directed ring-expansion in Schiff-base polypyrrolic macrocycles
Literature Information
Gonzalo Givaja, Alexander J. Blake, Claire Wilson, Martin Schröder, Jason B. Love
The reaction between a [2 + 2] Schiff-base porphyrin analogue and zinc acetate results in the unusual formation of an enlarged [3 + 3] macrocycle that is stabilised by metal coordination and intramolecular hydrogen-bonding interactions.
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