Towards the combinatorial synthesis of spongistatin fragment libraries by using asymmetric aldol reactions on solid support
Literature Information
Ian Paterson, Dirk Gottschling, Dirk Menche
By relying on asymmetric boron-mediated aldol reactions, solid phase methodology for the stereoselective synthesis of highly substituted spiroacetals was developed and applied to the preparation of a complex AB-spiroacetal subunit of the antimitotic agent spongistatin 1 (altohyrtin A).
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