Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination

Literature Information

Publication Date 2005-06-09
DOI 10.1039/B504519C
Impact Factor 6.222
Authors

Naoya Kumagai, Shigeki Matsunaga, Masakatsu Shibasaki


View Original

Abstract

The cooperative catalysis of CpRu(PPh3)2(CH3CN)PF6 (1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding β-hydroxynitriles 3 in good yield.

Related Literature

Back cover

2023-08-29 Cover

DOI: 10.1039/D3VA90033A

Monitoring of phosphorus discharge in a sewage treatment plant with a phosphate automated analyzer

Adrian Cabo, Susana Gouveia, Claudio Cameselle, Keun-Heon Lee

2022-08-01 Paper

DOI: 10.1039/D2VA00062H

Biochar implications in cleaner agricultural production and environmental sustainability

Subhash Babu, Raghavendra Singh, Sanjeev Kumar, Sanjay Singh Rathore, Devideen Yadav, Sanjay Kumar Yadav, Vivek Yadav, Meraj Alam Ansari, Anup Das, Gandhamanagenahalli Adireddy Rajanna, Owais Ali Wani, Rishi Raj, Dinesh Kumar Yadav, Vinod Kumar Singh

2023-06-01 Critical Review

DOI: 10.1039/D2VA00324D

Back cover

2023-02-06 Cover

DOI: 10.1039/D3VA90007J

Electrospun TiO2/carbon composite nanofibers as effective (photo)electrodes for removal and transformation of recalcitrant water contaminants

Ashley Hesterberg Butzlaff, Madeline Jensen, Chenxu Yan, Abdulsattar Ghanim, Charles Werth, David Cwiertny, Syed Mubeen

2023-05-04 Paper

DOI: 10.1039/D3VA00017F

The emergence of microplastics: charting the path from research to regulations

Scott Coffin

2023-02-01 Perspective

DOI: 10.1039/D2VA00275B

Aqueous ibuprofen sorption by using activated walnut shell biochar: process optimization and cost estimation

Manvendra Patel, Abhishek Kumar Chaubey, Charles U. Pittman, Jr., Dinesh Mohan

2022-07-19 Paper

DOI: 10.1039/D2VA00015F

Preparation, characterization, and methylene blue dye adsorption study of silk fibroin–graphene oxide nanocomposites

Lavita J. Martis, N. Parushuram, Y. Sangappa

2022-04-22 Paper

DOI: 10.1039/D1VA00047K

Multi-endpoint assessments for in vitro nano-bio interactions and uptake of biogenic phosphorus nanomaterials using HEK293 cells

Luis O. B. Afonso, Aaron G. Schultz, Amit Kumar Dinda

2023-03-11 Paper

DOI: 10.1039/D2VA00318J

You might also like

Compound Q&A

What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?

Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...

10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A

How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?

Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...

34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A

How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?

Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...

858-46-82,4,6-Tris(pentafluo...
Compound Q&A

What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?

When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...

56787-36-1Chloroac-nle-oh
Compound Q&A

What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?

Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...

752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A

Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?

Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...

55095-15-3alpha-(2-Bromophenyl...
Compound Q&A

How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?

Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...

139585-48-12-Chloro-5-methoxypy...
Compound Q&A

What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?

1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...

5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A

Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?

There are alternative reagents and compounds that can be used in the synthesis o...

903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A

What is Tungsten(IV) oxide (CAS: 12036-22-5)?

Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...

12036-22-5Tungsten(IV) oxide

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.