Hydrocarbon species μ3-CCH2−, μ3-CCH3 and μ-CHCH3 supported on Ti3O3

Literature Information

Publication Date 2005-06-16
DOI 10.1039/B504467G
Impact Factor 6.222
Authors

Octavio González-del Moral, Avelino Martín, Miguel Mena, María del Carmen Morales-Varela, Cristina Santamaría


View Original

Abstract

Treatment of the μ3-ethylidyne complex [{TiCp*(μ-O)}3(μ3-CMe)] (1), (Cp* = η5-C5Me5) with alkali metal amides leads to the oxoheterometallocubane derivatives [M(μ3-O)3{(TiCp*)3(μ3-CCH2)}] [M = Li (2), Na (3), K (4), Rb (5), Cs (6)] containing the naked carbanion μ3-CCH2−; the addition of triphenylmethanol and tert-butanol to the compounds 2–6 gives rise to the oxoderivatives [{TiCp*(μ-O)}3(μ-CHMe)(OCR3)] [R = Me (7), Ph (8)] which show a μ-ethylidene bridge on the surface model Ti3O3.

Related Literature

Back cover

2023-04-03 Cover

DOI: 10.1039/D3VA90013D

Back cover

2022-03-28 Cover

DOI: 10.1039/D2VA90004A

Maternal exposure to polystyrene nanoplastics impacts developmental milestones and brain structure in mouse offspring

Nikita E. Harvey, Grace V. Mercer, Darcie Stapleton, Katherine L. Steeves, Jenna Hanrahan, Megan Cui, Zahra Aghaei, Shoshana Spring, Paul A. Helm, André J. Simpson, Myrna J. Simpson, Ahmet A. Baschat, Karl J. Jobst

2023-02-15 Paper

DOI: 10.1039/D2VA00227B

Back cover

2023-05-09 Cover

DOI: 10.1039/D3VA90017G

Tracing the origin of elevated springtime atmospheric sulfate on the southern Himalayan-Tibetan plateau

Sanjeev Dasari, Guillaume Paris, Qiaomin Pei, Zhiyuan Cong, David Widory

2023-06-05 Paper

DOI: 10.1039/D3VA00085K

Planetary ball milling induced piezocatalysis for dye degradation using BaTiO3 ceramics

Akshay Gaur, Vishal Singh Chauhan, Rahul Vaish

2023-01-23 Paper

DOI: 10.1039/D2VA00210H

You might also like

Compound Q&A

What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?

Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...

10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A

How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?

Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...

34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A

How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?

Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...

858-46-82,4,6-Tris(pentafluo...
Compound Q&A

What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?

When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...

56787-36-1Chloroac-nle-oh
Compound Q&A

What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?

Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...

752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A

Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?

Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...

55095-15-3alpha-(2-Bromophenyl...
Compound Q&A

How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?

Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...

139585-48-12-Chloro-5-methoxypy...
Compound Q&A

What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?

1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...

5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A

Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?

There are alternative reagents and compounds that can be used in the synthesis o...

903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A

What is Tungsten(IV) oxide (CAS: 12036-22-5)?

Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...

12036-22-5Tungsten(IV) oxide

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.