Hydrocarbon species μ3-CCH2−, μ3-CCH3 and μ-CHCH3 supported on Ti3O3
Literature Information
Octavio González-del Moral, Avelino Martín, Miguel Mena, María del Carmen Morales-Varela, Cristina Santamaría
Treatment of the μ3-ethylidyne complex [{TiCp*(μ-O)}3(μ3-CMe)] (1), (Cp* = η5-C5Me5) with alkali metal amides leads to the oxoheterometallocubane derivatives [M(μ3-O)3{(TiCp*)3(μ3-CCH2)}] [M = Li (2), Na (3), K (4), Rb (5), Cs (6)] containing the naked carbanion μ3-CCH2−; the addition of triphenylmethanol and tert-butanol to the compounds 2–6 gives rise to the oxoderivatives [{TiCp*(μ-O)}3(μ-CHMe)(OCR3)] [R = Me (7), Ph (8)] which show a μ-ethylidene bridge on the surface model Ti3O3.
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