Infrared spectroscopic determination of the degree of charge transfer in complexes of TCNE with methyl-substituted benzenes

Literature Information

Publication Date 2005-06-09
DOI 10.1039/B504416B
Impact Factor 6.222
Authors

John C. Stires, IV, Emily J. McLaurin, Clifford P. Kubiak


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Abstract

The position of the CN stretching frequency in infrared spectra of tetracyanoethylene (TCNE) complexed with methyl-substituted benzenes is used to determine the fraction of charge transferred from the electron donor to the acceptor.

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Chemical Communications

Chemical Communications
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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