Rh(i)-catalyzed CO gas-free cyclohydrocarbonylation of alkynes with formaldehyde to α,β-butenolides

Literature Information

Publication Date 2005-06-01
DOI 10.1039/B503816B
Impact Factor 6.222
Authors

Koji Fuji, Tsumoru Morimoto, Ken Tsutsumi, Kiyomi Kakiuchi


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Abstract

The rhodium(I)-catalyzed reaction of alkynes with formaldehyde proceeds via the double incorporation of a carbonyl moiety from formaldehyde, resulting in a CO gas-free cyclohydrocarbonylation leading to α,β-butenolides.

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