Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis
Literature Information
Arjan W. Kleij, Martin Lutz, Anthony L. Spek, Piet W. N. M. van Leeuwen, Joost N. H. Reek
Encapsulated phosphane ligands can be easily constructed through coordinative interactions between Zn(II)–salphen complexes and pyridylphosphane templates; the template has a pronounced impact on the catalyst structure and consequently on the performance in the hydroformylation of 1-octene.
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