Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

Literature Information

Publication Date 2005-06-10
DOI 10.1039/B503708E
Impact Factor 6.222
Authors

Arjan W. Kleij, Martin Lutz, Anthony L. Spek, Piet W. N. M. van Leeuwen, Joost N. H. Reek


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Abstract

Encapsulated phosphane ligands can be easily constructed through coordinative interactions between Zn(II)–salphen complexes and pyridylphosphane templates; the template has a pronounced impact on the catalyst structure and consequently on the performance in the hydroformylation of 1-octene.

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Chemical Communications

Chemical Communications
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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