A Ru(terpy)(phen)-incorporating ring and its light-induced geometrical changes

Literature Information

Publication Date 2005-05-24
DOI 10.1039/B503411F
Impact Factor 6.222
Authors

Sylvestre Bonnet, Jean-Paul Collin, Jean-Pierre Sauvage


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Abstract

A Ru(terpy)(phen) motif has been inscribed in a 39-membered ring by functionalizing the ligands and subsequently performing a cyclization reaction on the complex; by visible light irradiation, a dramatic geometrical changeover of the cyclic complex takes place which can be reversed thermally.

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