Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues

Literature Information

Publication Date 2005-05-27
DOI 10.1039/B502850G
Impact Factor 6.222
Authors

Karena W. Chapman, Peter D. Southon, Colin L. Weeks, Cameron J. Kepert


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Abstract

The family of dehydrated nanoporous Prussian Blue analogues, MII3[CoIII(CN)6]2 (MII = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.

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