Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues
Literature Information
Karena W. Chapman, Peter D. Southon, Colin L. Weeks, Cameron J. Kepert
The family of dehydrated nanoporous Prussian Blue analogues, MII3[CoIII(CN)6]2 (MII = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.
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