Fourteen-vertex homo- and heterobimetallic metallacarboranes

Literature Information

Publication Date 2005-02-15
DOI 10.1039/B500236B
Impact Factor 6.222
Authors

David Ellis, Maria Elena Lopez, Ruaraidh McIntosh, Georgina M. Rosair, Alan J. Welch


View Original

Abstract

Reduction of 4-(p-cymene)-4,1,12-closo-RuC2B10H12 followed by metallation with {M′} fragments (M′ = {CpCo2+}, {(arene)Ru2+} or {(dppe)Ni2+}) affords 14-vertex bimetallic 1,14,2,10-RuM′C2B10 species having bicapped hexagonal antiprismatic structures.

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