The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis
Literature Information
Abhudaya Mishra, Wolfgang Wernsdorfer, Khalil A. Abboud, George Christou
Synthetic entry has been achieved into high oxidation state Mn–Ca cluster chemistry with the preparation of [Mn13Ca2O10(OH)2(OMe)2(O2CPh)18(H2O)4]; the structure contains [Mn4CaO4] sub-units similar to that found in the photosynthetic water oxidizing complex.
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