1,4-Dihydro-1,4-diphosphinine fused with two tetrathiafulvalenes

Literature Information

Publication Date 2004-11-09
DOI 10.1039/B412193G
Impact Factor 6.222
Authors

Narcis Avarvari, Marc Fourmigué


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Abstract

Electrochemical and theoretical investigations demonstrate through-bond interactions between two TTF moieties fused to a 1,4-dihydro-1,4-diphosphinine, for which the single crystal X-ray structure of the cis isomer is described together with that of a mixed-valent, charge-localized, radical cation salt with Mo6O192−, obtained upon electrocrystallization of the same cis isomer.

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