A dynamic supramolecular system exhibiting substrate selectivity in the catalytic epoxidation of olefins

Literature Information

Publication Date 2004-12-02
DOI 10.1039/B411978A
Impact Factor 6.222
Authors

Stefán Jónsson, Fabrice G. J. Odille, Per-Ola Norrby, Kenneth Wärnmark


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Abstract

A dynamic supramolecular system involving hydrogen bonding between a Mn(III) salen catalyst and a Zn(II) porphyrin receptor exhibits selectivity for pyridine appended cis-β-substituted styrene derivatives over phenyl appended derivatives in a catalytic epoxidation reaction.

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