CoII5(OH)6(SO4)2(H2O)4: the first ferromagnet based on a layered cobalt–hydroxide pillared by inorganic ⋯OSO3–Co(H2O)4–O3SO⋯

Literature Information

Publication Date 2004-10-06
DOI 10.1039/B411304G
Impact Factor 6.222
Authors

Serge Vilminot, Mireille Richard-Plouet, Gilles André, Tahar Mhiri, Mohamedally Kurmoo


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Abstract

The synthetic mineral CoII5(OH)6(SO4)2(H2O)4 (1), obtained by hydrothermal reaction of CoSO4·7H2O and NaOH at 165 °C and consisting of brucite-like Co4(OH)6O2 layers pillared by OSO3–Co(H2O)4–O3SO, is a ferromagnet (TCurie = 12 K, Hc = 580 Oe).

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