Molecular tectonics: design of luminescent H-bonded molecular networks

Literature Information

Publication Date 2004-09-07
DOI 10.1039/B410459P
Impact Factor 6.222
Authors

Sylvie Ferlay, Mir Wais Hosseini, Véronique Bulach, Jean-Marc Planeix


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Abstract

Using bis-amidinium dications as tetra H-bond donor tectons and Au(CN)2− anion, neutral 1-D networks based on a bis monohapto mode of H-bonding are obtained. Owing to the short metal–metal distance within the network, luminescent crystals are obtained. The emission phenomena may be tuned by the nature of the spacer connecting the two cyclic amidinium groups.

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