Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(i) centre

Literature Information

Publication Date 2004-08-25
DOI 10.1039/B409134E
Impact Factor 6.222
Authors

Angelino Doppiu, Ulli Englert, Albrecht Salzer


View Original

Abstract

The optically pure cationic complex (S,SRh)-[Rh(η5-C5H4CH2CH(Ph)PPh2-κP)(η2-CH2CH2)(CH3)][I] is the first example of a key intermediate in the oxidative addition reaction of methyl iodide on a rhodium(I) centre which has been structurally characterized by X-ray diffraction.

Related Literature

POSS semitelechelic Aβ17–19 peptide initiated helical polypeptides and their structural diversity in aqueous medium

Ujjal Haldar, Abhishek Pan, Ishita Mukherjee, Priyadarsi De

2016-09-16 Paper

DOI: 10.1039/C6PY01399F

1,3-Dipolar and Diels–Alder cycloaddition reactions on polyester backbones possessing internal electron-deficient alkyne moieties

Muge Cetin, Cansu Esen, Ozgun Daglar, Serter Luleburgaz, Gurkan Hizal, Hakan Durmaz, Umit Tunca

2016-10-27 Paper

DOI: 10.1039/C6PY01827K

Stimuli-responsive single-chain polymeric nanoparticles towards the development of efficient drug delivery systems

Chih-Chia Cheng, Zhi-Sheng Liao, Jyun-Jie Huang

2016-09-19 Communication

DOI: 10.1039/C6PY01623E

Micellar assembly of a photo- and temperature-responsive amphiphilic block copolymer for controlled release

Fang Yang, Ziquan Cao, Guojie Wang

2015-09-25 Paper

DOI: 10.1039/C5PY01435B

Anionic conjugated polytriazole: direct preparation, aggregation-enhanced emission, and highly efficient Al3+ sensing

Wenhui Dong, Haiqiang Wu, Ming Chen, Yang Shi, Jingzhi Sun

2016-08-29 Paper

DOI: 10.1039/C6PY01202G

Pyridine type zwitterionic polyurethane with both multi-shape memory effect and moisture-sensitive shape memory effect for smart biomedical application

Shaojun Chen, Zhankui Mei, Huanhuan Ren, Haitao Zhuo, Jianhong Liu, Zaochuan Ge

2016-07-26 Paper

DOI: 10.1039/C6PY01099G

Dual-responsive nanoparticles based on oxidized pullulan and a disulfide-containing poly(β-amino) ester for efficient delivery of genes and chemotherapeutic agents targeting hepatoma

Hemei Wang, Guoyun Wan, Bowei Chen, Hongli Chen, Sipei Zhang, Dan Wang, Qingqing Xiong, Yinsong Wang

2016-09-28 Paper

DOI: 10.1039/C6PY01664B

Correction: Titin-mimicking polycyclic polymers with shape regeneration and healing properties

Jan-Hendrik Schuetz, Wentao Peng, Philipp Vana

2015-02-17 Correction

DOI: 10.1039/C5PY90031J

Preparation of glucose responsive polyelectrolyte capsules with shell crosslinking via the layer-by-layer technique and sustained release of insulin

Dongjian Shi, Maoshuang Ran, He Huang, Li Zhang, Xiaojie Li, Mingqing Chen, Mitsuru Akashi

2016-10-10 Paper

DOI: 10.1039/C6PY01448H

You might also like

Compound Q&A

What is 1-(2,4,6-Trifluorophenyl)ethanol (CAS: 1250113-83-7)?

1-(2,4,6-Trifluorophenyl)ethanol is an organic compound with the CAS number 1250...

1250113-83-71-(2,4,6-Trifluoroph...
Compound Q&A

Is 1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) safe?

1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) is ...

919111-34-51-(2,4-Dimethoxybenz...
Compound Q&A

What are the physical and chemical properties of (7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one (CAS: 51419-51-3)?

(7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one is a crystal...

51419-51-3(7S,15R)-6β,15-Diace...
Compound Q&A

What regulatory guidelines apply to rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3618-04-0)?

The compound rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3...

3618-04-0rac-ethyl (1r,4r)-4-...
Compound Q&A

What is the market or research trend for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3)?

The market for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3) is cur...

175135-62-32-(2,4-Difluoropheno...
Compound Q&A

What are the main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9)?

The main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9) include research in ...

157-03-96-Diazo-5-oxo-L-norl...
Compound Q&A

What precautions should be taken when handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5)?

When handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5), i...

173308-19-52-Aminoethyl-mono-am...
Compound Q&A

How is 5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) typically synthesized?

5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) can be synthesi...

178488-37-45-Methylimidazo[1,2-...
Compound Q&A

Are there alternatives to 2,4,6-Trihydroxyisophthalaldehyde (CAS: 4396-13-8) in synthesis?

There are alternative reagents that can be used in the synthesis of 2,4,6-Trihyd...

4396-13-82,4,6-Trihydroxyisop...
Compound Q&A

What is (2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid (CAS: 179461-52-0)?

(2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid is a chemical compound wi...

179461-52-0(2Z)-3-(5-Fluoro-1H-...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.