Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(i) centre
Literature Information
Angelino Doppiu, Ulli Englert, Albrecht Salzer
The optically pure cationic complex (S,SRh)-[Rh(η5-C5H4CH2CH(Ph)PPh2-κP)(η2-CH2CH2)(CH3)][I] is the first example of a key intermediate in the oxidative addition reaction of methyl iodide on a rhodium(I) centre which has been structurally characterized by X-ray diffraction.
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![1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure 1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure](https://static.chemtradehub.com/structs/97-/97-77-8-f3e4.webp)
