En route to coordination chemistry under confined conditions in a porous capsule: Pr3+ with different coordination shells

Literature Information

Publication Date 2004-08-13
DOI 10.1039/B407753A
Impact Factor 6.222
Authors

Achim Müller, Yunshan Zhou, Lijuan Zhang, Hartmut Bögge, Marc Schmidtmann, Martin Dressel, Joris van Slageren


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Abstract

The highly charged nanocontainer capsule of the type {pentagon}12{linker}30 ≡ {(Mo)Mo5O21(H2O)6}12{Mo2O4 (SO4)}30 with 20 nanosized pores and channels allows the entrance of cations like Pr3+: the latter are positioned at two different sites and have two different coordination shells, corresponding to a coordination chemistry under confined conditions; a fascinating aspect is that capsule encapsulated water shells fixed by hydrogen bonds act formally as polydentate ligands.

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Cover

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Contents list

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Chemical Communications
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