Oligomer preparation from hexane by radical polyaddition with bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate

Literature Information

Publication Date 2004-09-07
DOI 10.1039/B406116K
Impact Factor 6.222
Authors

Tadashi Narita, Hiroshi Hamana, Satoshi Hattori


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Abstract

Polymer preparation from hexane as a starting material by radical polyaddition with bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate [CF2C(CF3)OCOC6H4COO–C(CF3)CF2] was investigated to afford polymers bearing a molecular weight of as high as 5.5 × 103, and the polyaddition mechanism including 1,5-radical shift mechanism was proposed.

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