Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: Application in the synthesis of 1,3-diphosphafulvenes

Literature Information

Publication Date 2004-05-04
DOI 10.1039/B403436H
Impact Factor 6.222
Authors

Thibault Cantat, Nicolas Mézailles, Nicole Maigrot, Louis Ricard, Pascal Le Floch


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Abstract

Titanocene and zirconocene carbene complexes of a phosphorus equivalent of an Arduengo's carbene have been synthesized in the coordination sphere of titanocene and zirconocene and exhibit a nucleophilic character which has been exploited in the synthesis of 1,3-diphosphafulvenes.

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