K6Cd4Sn3Se13: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10− cluster

Literature Information

Publication Date 2004-04-23
DOI 10.1039/B402686A
Impact Factor 6.222
Authors

Nan Ding, Duck-Young Chung, Mercouri G. Kanatzidis


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Abstract

K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13]6− cluster which formally derives from a [Cd4Sn4Se17]10−via elimination of one [SnSe4]4− anion. K6Cd4Sn3Se13 exhibits facile ion-exchange properties with suitably sized cations.

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