Convenient syntheses of “heavy fluorous” cyclopentadienes and cyclopentadienyl complexes with three to five ponytails

Literature Information

Publication Date 2004-03-17
DOI 10.1039/B401540A
Impact Factor 6.222
Authors

Long V. Dinh, J. A. Gladysz


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Abstract

Reactions of (η5-C5H5−xBrx)M(CO)3 (M = Re, Mn; x = 1, 3, 4, 5) and IZn(CH2)2Rf8 in the presence of Cl2PdL2 catalysts give the title complexes (η5-C5H5−x((CH2)2Rf8)x)M(CO)3, accompanied in the case of x = 5 by hydride-transfer byproducts. Extremely high fluorophilicities are realized, and the cyclopentadienyl ligands are readily detached (hν) from the manganese complexes.

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