Convenient syntheses of “heavy fluorous” cyclopentadienes and cyclopentadienyl complexes with three to five ponytails
Literature Information
Long V. Dinh, J. A. Gladysz
Reactions of (η5-C5H5−xBrx)M(CO)3 (M = Re, Mn; x = 1, 3, 4, 5) and IZn(CH2)2Rf8 in the presence of Cl2PdL2 catalysts give the title complexes (η5-C5H5−x((CH2)2Rf8)x)M(CO)3, accompanied in the case of x = 5 by hydride-transfer byproducts. Extremely high fluorophilicities are realized, and the cyclopentadienyl ligands are readily detached (hν) from the manganese complexes.
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![2-[(5Z,8Z,11Z,14Z)-5,8,11,14-Icosatetraen-1-yloxy]-1,3-propanediol structure 2-[(5Z,8Z,11Z,14Z)-5,8,11,14-Icosatetraen-1-yloxy]-1,3-propanediol structure](https://static.chemtradehub.com/structs/222/222723-55-9-0348.webp)

![(4aR,5S,6R,8aS)-5-[2-(3-Furyl)ethyl]-8a-(hydroxymethyl)-5,6-dimethyl-3,4,4a,5,6,7,8,8a-octahydro-1-naphthalenecarboxylic acid structure (4aR,5S,6R,8aS)-5-[2-(3-Furyl)ethyl]-8a-(hydroxymethyl)-5,6-dimethyl-3,4,4a,5,6,7,8,8a-octahydro-1-naphthalenecarboxylic acid structure](https://static.chemtradehub.com/structs/184/18411-75-1-d4cd.webp)
