Cycloaddition of phosphanylidene-σ4-phosphoranes ArPPMe3 and quinones to yield 1,3,2-dioxophospholanes

Literature Information

Publication Date 2003-11-21
DOI 10.1039/B309165A
Impact Factor 6.222
Authors

Xufang Chen, Rhett C. Smith, John D. Protasiewicz


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Abstract

The reaction of phosphanylidene-σ4-phosphoranes ArPPMe3 (Ar = 2,6-Mes2C6H3 or 2,4,6-t-Bu3C6H2) with select ortho-quinones yields 1,3,2-dioxophospholanes, one of which shows interesting π-stacking of the aromatic groups in the solid state.

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