Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand
Literature Information
Markus Albrecht, Sören Schmid, Marita deGroot, Patrick Weis, Roland Fröhlich
Chiral tetraketone ligands are obtained by Claisen-type condensation of 4-bromoacetophenone with the acetone ketal of L-tartraic acid diethylester and lead with gallium(III) or iron(III) ions in self-assembly processes to dinuclear helicate-type cryptands which are able to bind lithium cations.
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