Concise total synthesis of the aporphine alkaloid 7,7′-bisdehydro-O-methylisopiline by an InCl3 mediated cycloisomerization reaction
Literature Information
Publication Date
2003-07-22
DOI
10.1039/B306880C
Impact Factor
6.222
Authors
Alois Fürstner, Victor Mamane
View Original
Abstract
A novel InCl3 mediated cycloisomerization reaction leading to 10-halophenanthrene derivatives constitutes the key step of the first total syntheses of O-methyldehydroisopiline 10 and 7,7′-bisdehydro-O-methylisopiline 11, two prototype members of the aporphine family of alkaloids.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
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methyl 6-amino-1H-pyrrolo[2,3-b]pyridine-4-carboxylate
CAS Number:
1190315-60-6
Molecular Formula:
C9H9N3O2
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3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol
CAS Number:
861249-77-6
Molecular Formula:
C17H13N5O
(3-Amino-piperidin-1-yl)-thiophen-3-yl-methanone hydrochloride
CAS Number:
1185316-70-4
Molecular Formula:
C10H15ClN2OS
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