A mixed-valence compound with one unpaired electron delocalized over four molybdenum atoms in a cyclic tetranuclear ion
Literature Information
F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, Xiaoping Wang
The first oxidation of a species derived from a compound having two linked, quadruply-bonded Mo2 units has been performed and [[cis-Mo2(DAniF)2]2(μ-Cl)4]PF6, 2, has been isolated and characterized in many ways; it has one unpaired electron and a fully delocalized structure where the Mo–Mo distances increase from 2.1191(4) Å in the reduced species to 2.1453(3) Å in 2 and the Kc of 1.3 × 109 is three orders of magnitude larger than that of the Creutz–Taube ion.
Related Literature
A review on MXenes: new-generation 2D materials for supercapacitors
G. Murali, Jishu Rawal, Jeevan Kumar Reddy Modigunta, Young Ho Park, Jong-Hoon Lee, Soo-Jin Park, Insik In
DOI: 10.1039/D1SE00918D
Use of a Lewis acid, a Brønsted acid, and their binary mixtures for the liquefaction of lignocellulose by supercritical ethanol processing
Koray Alper, Yun-Yan Wang, Xianzhi Meng, Kubilay Tekin, Selhan Karagoz
DOI: 10.1039/D1SE01316E
High hydrogen release catalytic activity by quasi-MOFs prepared via post-synthetic pore engineering
Minoo Bagheri, Mohammad Yaser Masoomi, Esther Domínguez, Hermenegildo García
DOI: 10.1039/D1SE00661D
Salt screening analysis for reverse electrodialysis
Jamie Hestekin
DOI: 10.1039/D1SE01447A
Metal fuel production through the solar carbothermal reduction of magnesia: effect of the reducing agent
Youssef Berro, Damaris Kehrli, Jean-François Brilhac, Marianne Balat-Pichelin
DOI: 10.1039/D1SE01549D
How sustainable is CO2 conversion to ethanol? – A life cycle assessment of a new electrocatalytic carbon utilisation process
Daniel Rojas Sánchez, Kaveh Khalilpour, Andrew F. A. Hoadley
DOI: 10.1039/D1SE01462E
A novel Ba0.95La0.05Fe0.9Nb0.1O3−δ ceramic electrode for symmetrical solid oxide fuel cells
Zhongbiao Li, Jinpeng Wang, Jiangpeng Zhu, Yanjun Sun, Zhihao Wang, Yujun Zhao, Qiuju Zheng
DOI: 10.1039/D1SE01291F
You might also like
What precautions should be taken when handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-57-1)?
When handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-5...
What are the physical and chemical properties of 5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9)?
5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9) is a crystalline solid ...
How should (2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) be stored?
(2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) should be stored in a c...
What regulatory guidelines apply to Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 362707-24-2)?
Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 3627...
What are the main uses of 1,4-dimethyl-1H-pyrazole-5-sulfonyl chloride (CAS: 1174834-52-6)?
1,4-Dimethyl-1H-pyrazole-5-sulfonyl chloride is primarily used as an intermediat...
Is Dinaphtho[1,2-b:2',1'-d]furan (CAS: 239-69-0) safe?
Dinaphtho[1,2-b:2',1'-d]furan is generally safe when handled with appropriate pe...
What is the market or research trend for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3)?
The market for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3) i...
What are the physical and chemical properties of 2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1)?
2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1) is a colorless or light yello...
How is 2-Methylchrysene (CAS: 3351-32-4) typically synthesized?
2-Methylchrysene (CAS: 3351-32-4) is typically synthesized via the reaction of c...
Is N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) safe?
N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) is generally considered saf...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry













![3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure 3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure](https://static.chemtradehub.com/structs/861/861249-77-6-025b.webp)
