An unprecedented mode of ligation for a bridged amido-cyclopentadienide (constrained geometry) ligand; π-olefinic interactions with gallium and indium
Literature Information
Jeffrey M. Pietryga, Jamie N. Jones, Lucille A. Mullins, Robert J. Wiacek, Alan H. Cowley
The surprising reaction of GaCl3 or InBr3 with the di-Grignard reagent [Me2Si(C5Me4)(N-t-Bu)](MgCl)2·THF results in salts of the bimetallic anions of composition [X3M{C5Me4 (N-t-Bu)}MX2]− (M = Ga, X = Cl; M = In; X = Br) in which the MX2 moiety undergoes an η2-interaction with one of the double bonds of the localized cyclopentadienide ring.
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