A facile tetrahydrothiophene-catalyzed ylide route to vinyloxiranes

Literature Information

Publication Date 2003-07-10
DOI 10.1039/B304443B
Impact Factor 6.222
Authors

Kai Li, Xian-Ming Deng, Yong Tang


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Abstract

Access to vinyloxiranes using aldehydes and allylic bromides in the presence of 1–5 mol% tetrahydrothiophene is reported. Both aliphatic and aromatic aldehydes work well in this reaction and the catalyst loading could be reduced as low as 0.5 mol%.

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Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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