Neutral and dianionic iron and ruthenium 1,4-diphosphabutadiene complexes
Literature Information
Audrey Moores, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch
Reaction of a tetraphenyl-1,2-diphosphinyl dianion with [FeCl2(THF)1.5] or [Ru(COD)(acac)2] yields dianionic complexes which further react with Ph3SnCl to afford the corresponding bis(1,4-diphosphabutadiene) complexes.
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