Neutral and dianionic iron and ruthenium 1,4-diphosphabutadiene complexes

Literature Information

Publication Date 2003-06-26
DOI 10.1039/B304243J
Impact Factor 6.222
Authors

Audrey Moores, Nicolas Mézailles, Louis Ricard, François Mathey, Pascal Le Floch


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Abstract

Reaction of a tetraphenyl-1,2-diphosphinyl dianion with [FeCl2(THF)1.5] or [Ru(COD)(acac)2] yields dianionic complexes which further react with Ph3SnCl to afford the corresponding bis(1,4-diphosphabutadiene) complexes.

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