The seventeen- and eighteen-electron metallacarbaboranes [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]n− (n = 1, 2): a structurally characterized, redox-related pair
Literature Information
Shaowu Du, Robert D. Farley, Jeremy N. Harvey, John C. Jeffery, Jason A. Kautz, John P. Maher, Thomas D. McGrath, Damien M. Murphy, T. Riis-Johannessen, F. Gordon A. Stone
An eleven-vertex manganese-monocarbaborane dianion, upon one-electron oxidation, gives a stable radical monoanion in which the unpaired electron is delocalized over the cluster.
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