A highly deformed iron(ii) low-spin phthalocyanine which shows two MLCT transitions beyond the Q-band

Literature Information

Publication Date 2003-06-03
DOI 10.1039/B303991A
Impact Factor 6.222
Authors

Takamitsu Fukuda, Shigetsugu Homma, Nagao Kobayashi


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Abstract

A highly deformed [1,4,8,11,15,18,22,25-octaphenylphthalo-cyaninato(2-)]iron(II) has been synthesized, and found to show absorption bands which may be assigned to metal-to-ligand charge transfer (MLCT) transitions in the near-IR region beyond the Q-band in pyridine, due to lowering of molecular symmetry to D2d from D4h symmetry of normal metallophthalocyanines.

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