Crystal structure of mono[3-(2-imidazolylthio)]-altro-β-cyclodextrin: elliptical distortion of the cavity and unique ‘Yin–Yang’ stacking‡
Literature Information
Hans J. Lindner, De-Qi Yuan, Kahee Fujita, Koushi Kubo, Frieder W. Lichtenthaler
The title compound is elliptically distorted due to the unusual 1C4 geometry of the altrose portion. In packing, a unique fourfold helical structure is elaborated with head-to-head dimers as the repeating motif. The imidazolyl moieties mutually reside on each other's cavities thereby resembling the Yin–Yang type balancing of antagonisms.
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