Crystal structure of mono[3-(2-imidazolylthio)]-altro-β-cyclodextrin: elliptical distortion of the cavity and unique ‘Yin–Yang’ stacking‡

Literature Information

Publication Date 2003-06-05
DOI 10.1039/B303788F
Impact Factor 6.222
Authors

Hans J. Lindner, De-Qi Yuan, Kahee Fujita, Koushi Kubo, Frieder W. Lichtenthaler


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Abstract

The title compound is elliptically distorted due to the unusual 1C4 geometry of the altrose portion. In packing, a unique fourfold helical structure is elaborated with head-to-head dimers as the repeating motif. The imidazolyl moieties mutually reside on each other's cavities thereby resembling the Yin–Yang type balancing of antagonisms.

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