Ba2−xSrxPdO2F2 (0 ≤ x ≤ 1.5): The first palladium–oxide–fluorides

Literature Information

Publication Date 2003-05-29
DOI 10.1039/B303402J
Impact Factor 6.222
Authors

Thomas Baikie, Emma L. Dixon, John F. Rooms, Nigel A. Young, M. Grazia Francesconi


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Abstract

The first series of alkaline-earth palladium oxide–fluorides Ba2−xSrxPdO2F2 (0 ≤ x ≤ 1.5) display the T′ structure (Nd2CuO4) instead of the predicted T structure (La2CuO4), showing that electronic factors prevail over steric factors.

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