Mechanism of ruthenium-catalyzed hydrogen transfer reactions. Evidence for a stepwise transfer of CH and NH hydrogens from an amine to a (cyclopentadienone)ruthenium complex

Literature Information

Publication Date 2003-06-10
DOI 10.1039/B303258B
Impact Factor 6.222
Authors

Alida H. Éll, Jeffrey B. Johnson, Jan-E. Bäckvall


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Abstract

Kinetic deuterium isotope effects and racemization studies indicate that dehydrogenation of an amine by a (cyclopentadienone)ruthenium complex occurs via a slow β-hydride elimination of coordinated amine followed by a proton transfer from nitrogen to carbonyl oxygen.

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Contents pages

Other

DOI: 10.1039/JA99106BX007

Front cover

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DOI: 10.1039/JA98601FX001

Back matter

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DOI: 10.1039/JA99005BP019

Hilger Spectroscopy Prize for 1989

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DOI: 10.1039/JA990050097A

Front cover

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DOI: 10.1039/JA99308FX015

Book review

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DOI: 10.1039/JA993080062N

Glossary of abbreviations

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DOI: 10.1039/JA990050074R

Editorial

Editorial

DOI: 10.1039/JA993080001N

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