Mechanism of ruthenium-catalyzed hydrogen transfer reactions. Evidence for a stepwise transfer of CH and NH hydrogens from an amine to a (cyclopentadienone)ruthenium complex

Literature Information

Publication Date 2003-06-10
DOI 10.1039/B303258B
Impact Factor 6.222
Authors

Alida H. Éll, Jeffrey B. Johnson, Jan-E. Bäckvall


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Abstract

Kinetic deuterium isotope effects and racemization studies indicate that dehydrogenation of an amine by a (cyclopentadienone)ruthenium complex occurs via a slow β-hydride elimination of coordinated amine followed by a proton transfer from nitrogen to carbonyl oxygen.

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Chemical Communications

Chemical Communications
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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