Concerted interaction between conjugated double bond CHs and multiple OHs in polyene macrolide antibiotic chainin: weak C–H⋯O interactions responsible for intrinsic molecular assembly

Literature Information

Publication Date 2003-06-12
DOI 10.1039/B303047D
Impact Factor 6.222
Authors

Yasuko In, Hirofumi Ohishi, Toshimasa Ishida, Yasuhiro Igarashi


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Abstract

The concerted interactions observed between five conjugated double bond CHs and four hydroxy Os in the crystal of chainin, a polyene macrolide antibiotic, clarified the existence of unprecedented, weak C–H⋯O interactions, which is important for forming its intrinsic molecular assembly.

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