Primary charge separation in photoinduced multielectron storage systems. A dinuclear ruthenium(ii) species featuring a charge-separated state with a lifetime of 1.3 µs

Literature Information

Publication Date 2003-06-06
DOI 10.1039/B302962J
Impact Factor 6.222
Authors

Sandro Fracasso, Sebastiano Campagna, Scolastica Serroni, Rama Konduri, Frederick M. MacDonnell


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Abstract

The primary photoinduced charge separation and recombination processes occurring in a dinuclear Ru(II) complex capable to perform multielectron storage upon light excitation have been studied in different solvents: the charge-separated state obtained in dichloromethane is, to the best of our knowledge, the longest-lived ever reported for a ruthenium polypyridine complex.

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