The structure of a self-assembled calixarene aqua-channel system

Literature Information

Publication Date 2003-03-03
DOI 10.1039/B301460F
Impact Factor 6.222
Authors

Anthony W. Coleman, Eric Da Silva, Farid Nouar, Martine Nierlich, Alda Navaza


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Abstract

The crystal structure of the complex 12.calix-[4]-arene dihydroxyphosphonic acid, 12.propane diammonium, 12.ethanol and 40.water molecules is based on dimeric units of the calix, assembled via trigonal units into a hexameric tube of 15 Å radius and 16 Å depth, further assemby via spanning propane diammonium cations and ethanol molecules forms a channel (40 Å), selectively containing all the water molecules.

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Chemical Communications

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