Synthesis, structure and reductive dechlorination of the C-centred phosphorus(iii) β-diketiminate PCl(Ph)L [L = C{C(Me)NC6H3Pri2-2,6}{C(Me)NHC6H3Pri2-2,6}]
Literature Information
Peter B. Hitchcock, Michael F. Lappert, Jacek E. Nycz
Treatment of the β-diketimine HL with successively LiBun and PCl2Ph gave the first C–centered monodentate β-diketiminate PCl(Ph)L 1; with C8K 1 underwent reductive dechlorination yielding 2, a novel N–PIII–PIII–CC heterocycle.
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